POTASSIUM, RADIOACTIVE:  Nuclear Power Plant Emissions

Plant Concentrations :
Potassium-40 concentrations in plants collected from Livingston Island (Antarctic Regions) were 34.7, 64, 374, and 131 Bq/kg wet weight, in mosses (genus Bryum), lichens (Usnea antarica), algae (Gigartina papillosa), and algae (genus Desmarestia), respectively(1). Potassium-40 levels in wild and edible plants in the vicinity of the Kozloduy nuclear power plant in Bulgaria were 950, 2130, and 1400 Bq/kg in Taraxacum officinale, Plantago lanceolata, and Populus nigras Italica, respectively, detection limit of 360 mBk/kg(2).
[(1) Baeza A et al; Bull Environ Contam Toxicol 25: 117-24 (1994) (2) Djingova R, Kuleff I; J Environ Radioactvity 59: 61-73 (2002) ]**PEER REVIEWED**


Sediment/Soil Concentrations :
SOIL: Potassium-40 concentrations in rocks range from 70-1,500 Bq/kg(1). Average concentrations of potassium-40 in continental crust and soil are 850 and 400 Bq/kg, respectively(1). Average concentration of potassium-40 in igneous rocks, sandstones, shales, and limestones are 810, 330, 810, and 81 Bq/kg, respectively(1). A study to determine radionulcides in soil within a 0-15km radius from coal-fired power plants in Melnik and Hodonin and a nuclear plant in Dukovany, Czechoslovakia found no relevant increase in soil concentration of potassium-40 even though the radionuclide is present in fly ash(2). Average activity in soil samples collected and analyzed from 1976 through 1978 were 2.0%, 1.5%, and 2.0% in the vicinity of the plants at Melnik, Hodonin, and Dukovany, respectively(2).
[(1) Eisenbud M, Gesell T, eds; Environmental radioactivity. 4th ed. San Diego: Academic Press. pp. 134-200 (1997) (2) Mejstrik V, Svacha J; Environ Geol 36: 305-19 (1988) ]**PEER REVIEWED**


Food Survey Values :
Potassium-40 is the predominant radioactive component in most foods(1,2). Seafood collected from the Ligurian Sea (Northern Italy) after the Chernobyl accident contained mean potassium-40 concentrations ranging from 122.6 to 164.0 Bq/kg wet weight in Smallspotted catshark (Scyliorhinus canicula) and Hake (Merluccius merluccius), respectively(3). The mean concentration of potassium-40 in composite samples of wild edible mushrooms collected from 1985-1997 from coniferous forests around the Nuclear Centre of Mexico was 1,021 Bq/kg dry weight(4). A mean potassium-40 concentration of 83.1 Bq/kg (range 39.1 to 132.9 Bq/kg) was reported for 39 honey samples collected 12 years after the Chernobyl accident(5). Average potassium-40 concentrations of 22.0 and 23.6 Bq/kg were reported in honey from areas around Warsaw, Poland in 1989 and in the Piedmontese (Italy) in 1987(5). Foods purchased during the US FDA's Total Diet Study, conducted from 1991 to 1997 were analyzed for radionulcides, including potassium-40; results indicated trace amounts present consistent with the near disappearance of contamination from nuclear weapons testing conducted during the early 1960s(6).
[(1) Argonne National Laboratory/EVS. Human Health Fact Sheet, August 2005. Potassium-40. Available at: http://www.ead.anl.gov/pub/doc/potassium.pdf as of Dec 29, 2005. (2) Eisenbud M, Gesell T, eds; Environmental radioactivity. 4th ed. San Diego: Academic Press. pp. 171-172 (1997) (3) Gallelli G et al; Sci Total Environ 196: 163-70 (1997) (4) Gaso MI et al; Sci Total Environ 223: 119-29 (1998) (5) Borawska MH et al; Bull Environ Contam Toxicol 64: 617-21 (2000) (6) Capar SG et al; J AOAC Int 83: 157-77 (2000) ]**PEER REVIEWED**


Food Survey Values :
Potassium-40 levels in edible plants from South Bulgaria(1).

Plant Mean Concentrations (Bq/kg)
Onion 148-329                
Cabbage 59-60                
Potatoes 98-160                
Tomatoes 57-163                
Peppers 63-100                
Grapes 30                
Corn 100                

[(1) Djingova R, Kuleff I; J Environ Radioactvity 59: 61-73 (2002) ]**PEER REVIEWED**


Disposal Methods :
SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.
**PEER REVIEWED**


Other Chemical/Physical Properties :
Potassium-40: Atomic weight: 39.9639987; natural abundance: 0.0117%; half-life: 1.26X10+9 years; decay mode: negative beta emission, 1.3111 MeV
[Lide, D.R. CRC Handbook of Chemistry and Physics 86TH Edition 2005-2006. CRC Press, Taylor & Francis, Boca Raton, FL 2005, p. 11-59]**PEER REVIEWED**


Other Chemical/Physical Properties :
Potassium-40 (0.0117% naturally occurring isotope), half-life 1.248X10-9 years, decays via beta emission (89.28%), 1.311 MeV to calcium-40, half-life stable; decays via electron capture (10.72%), 1.505 MeV to argon-40, half-life stable
[IAEA; NuDat 2.1. Brookhaven National Laboratory. National Nuclear Data Center. Inter Atomic Energy Agency, Nuclear Data Sect. Vienna, Austria. Available at http://www-nds.iaea.org/nudat2/index.jsp as of Aug 21, 2006. ]**PEER REVIEWED**


Other Chemical/Physical Properties :
Potassium-42, half-life 12.32 hrs, decays via beta(-) emission (3525.45 keV) to calcium-42, half-life stable.
[IAEA; NuDat 2.1. Brookhaven National Laboratory. National Nuclear Data Center. Inter Atomic Energy Agency, Nuclear Data Sect. Vienna, Austria. Available at http://www-nds.iaea.org/nudat2/index.jsp as of Aug 21, 2006. ]**PEER REVIEWED**


Other Chemical/Physical Properties :
Potassium-43, half-life 22.3 hrs, decays via beta(-) emission (1815 keV) to calcium-43, half-life stable
[IAEA; NuDat 2.1. Brookhaven National Laboratory. National Nuclear Data Center. Inter Atomic Energy Agency, Nuclear Data Sect. Vienna, Austria. Available at http://www-nds.iaea.org/nudat2/index.jsp as of Aug 21, 2006. ]**PEER REVIEWED**


Radiation Limits & Potential :
Potassium-40 (0.0117% naturally occurring isotope), half-life 1.248x10-9 years, decays via beta emission (89.28%), 1.311 MeV to calcium-40, half-life stable; decays via electron capture (10.72%), 1.505 MeV to argon-40, half-life stable
[IAEA; NuDat 2.1. Brookhaven National Laboratory. National Nuclear Data Center. Inter Atomic Energy Agency, Nuclear Data Sect. Vienna, Austria. Available at http://www-nds.iaea.org/nudat2/index.jsp as of Aug 21, 2006. ]**PEER REVIEWED**


Radiation Limits & Potential :
Potassium-42, half-life 12.32 hrs, decays via beta(-) emission (3525.45 keV) to calcium-42, half-life stable.
[IAEA; NuDat 2.1. Brookhaven National Laboratory. National Nuclear Data Center. Inter Atomic Energy Agency, Nuclear Data Sect. Vienna, Austria. Available at http://www-nds.iaea.org/nudat2/index.jsp as of Aug 21, 2006. ]**PEER REVIEWED**


Radiation Limits & Potential :
Potassium-43, half-life 22.3 hrs, decays via beta(-) emission (1815 keV) to calcium-43, half-life stable
[IAEA; NuDat 2.1. Brookhaven National Laboratory. National Nuclear Data Center. Inter Atomic Energy Agency, Nuclear Data Sect. Vienna, Austria. Available at http://www-nds.iaea.org/nudat2/index.jsp as of Aug 21, 2006. ]**PEER REVIEWED**

MORE ABOUT HEALTH EFFECTS

Human Toxicity Excerpts:
/OTHER TOXICITY INFORMATION/ Potassium-40, which is the inseparable radioactive component of natural, biologically important potassium, will probably cause the largest portion of the internal dose ... in the fetus because it doesn't breathe.
[DHHS/ATSDR; Toxicological Profile for Ionizing Radiation p.153 (PB/99/163388) (1999) ]**PEER REVIEWED**

/OTHER TOXICITY INFORMATION/ The diffusion coefficients for the exchange of potassium across the membrane of erythrocytes of humans ... have been determined by the use of artificially radioactive potassium, both into and out of the erythrocytes both in vitro and in vivo. The diffusion coefficients found in minutes were 0.2 to 0.25x10-3 ...
[Dean RB et al; J Gen Physiol 24: 353-65 (1941) ]**PEER REVIEWED**


Probable Routes of Human Exposure:
As there are no specific commercial or medical uses for potassium-40(1), occupational exposure is not expected(SRC). The general population will be exposed via ingestion(2) to potassium-40(SRC), since potassium-40 is present in small amounts (0.012%) in potassium, which is found widely in the environment(1). Occupational exposure to potassium-42 and -43 may occur via dermal contact; general population exposure may be limited to those being administered these radioisotopes as a result of medical applications(SRC).
[(1) Argonne National Laboratory/EVS. Human Health Fact Sheet, August 2005. Potassium-40. Available at: http://www.ead.anl.gov/pub/doc/potassium.pdf as of Dec 29, 2005. (2) DHHS/ATSDR; Toxicological Profile for Ionizing Radiation p.249 (PB/99/163388) (1999) ]**PEER REVIEWED**


Body Burden:
The body content of potassium is under strict homeostatic control and is maintained at a relatively constant level of about 140 g/70 kg. This amount of potassium contains approximately 0.1 uCi (4,000 Bq) of potassium-40. Because the body controls the potassium balance, environmental variations have little effect on the potassium-40 content in the body. This natural potassium-40 delivers a dose of 20 mrem/year (0.2 mSv/year) to the gonads and other soft tissues and 15 mrem/year (0.15 mSv/year) to bone.
[DHHS/ATSDR; Toxicological Profile for Ionizing Radiation p.241 (PB/99/163388) (1999) ]**PEER REVIEWED**

Potassium-40 is the predominant radioactive component in human tissues(1). The potassium-40 content in the human body is on the order of 0.1 uCi(1). However, because the body controls the potassium balance, variations in environmental levels have little effect on the potassium-40 content in the body(2).
[(1) Eisenbud M, Gesell T, eds; Environmental radioactivity. 4th ed. San Diego: Academic Press. pp. 171-172 (1997) (2) DHHS/ATSDR; Toxicological Profile for Ionizing Radiation p.249 (PB/99/163388) (1999) ]**PEER REVIEWED**


Probable Routes of Human Exposure:
As there are no specific commercial or medical uses for potassium-40(1), occupational exposure is not expected(SRC). The general population will be exposed via ingestion(2) to potassium-40(SRC), since potassium-40 is present in small amounts (0.012%) in potassium, which is found widely in the environment(1). Occupational exposure to potassium-42 and -43 may occur via dermal contact; general population exposure may be limited to those being administered these radioisotopes as a result of medical applications(SRC).
[(1) Argonne National Laboratory/EVS. Human Health Fact Sheet, August 2005. Potassium-40. Available at: http://www.ead.anl.gov/pub/doc/potassium.pdf as of Dec 29, 2005. (2) DHHS/ATSDR; Toxicological Profile for Ionizing Radiation p.249 (PB/99/163388) (1999) ]**PEER REVIEWED**


Body Burden:
The body content of potassium is under strict homeostatic control and is maintained at a relatively constant level of about 140 g/70 kg. This amount of potassium contains approximately 0.1 uCi (4,000 Bq) of potassium-40. Because the body controls the potassium balance, environmental variations have little effect on the potassium-40 content in the body. This natural potassium-40 delivers a dose of 20 mrem/year (0.2 mSv/year) to the gonads and other soft tissues and 15 mrem/year (0.15 mSv/year) to bone.
[DHHS/ATSDR; Toxicological Profile for Ionizing Radiation p.241 (PB/99/163388) (1999) ]**PEER REVIEWED**

Potassium-40 is the predominant radioactive component in human tissues(1). The potassium-40 content in the human body is on the order of 0.1 uCi(1). However, because the body controls the potassium balance, variations in environmental levels have little effect on the potassium-40 content in the body(2).
[(1) Eisenbud M, Gesell T, eds; Environmental radioactivity. 4th ed. San Diego: Academic Press. pp. 171-172 (1997) (2) DHHS/ATSDR; Toxicological Profile for Ionizing Radiation p.249 (PB/99/163388) (1999) ]**PEER REVIEWED**

All of the above is directly from
http://toxnet.nlm.nih.gov/

www.frankmckinnon.com